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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions

Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...
Carroll, S. et al Lawrence Livermore National Laboratory
Jul 01, 2013
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Chlorite, Biotite, Illite, Muscovite and Feldspar Dissolution Kinetics at Variable pH and Temperatures up to 280 deg C

Chemical reactions pose an important but poorly understood threat to EGS long-term success because of their impact on fracture permeability. This report summarizes the dissolution rate equations for layered silicates where data were lacking for geothermal systems. Here we report ...
Carroll, S. et al Lawrence Livermore National Laboratory
Feb 24, 2017
2 Resources
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Simulation Tools for Modeling Thermal Spallation Drilling on Multiple Scales

Widespread adoption of geothermal energy will require access to deeply buried resources in granitic basement rocks at high temperatures and pressures. Exploiting these resources necessitates novel methods for drilling, stimulation, and maintenance, under operating conditions that ...
Walsh, S. et al Lawrence Livermore National Laboratory
Jan 01, 2012
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Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C

FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Oct 01, 2013
2 Resources
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Sustainable Self-Propping Shear Zones in EGS: Chlorite, Illite, and Biotite Rates and Report

Spreadsheet containing chlorite, illite, and biotite rate data and rate equations that can be used in reactive transport simulations. Submission includes a report on the development of the rate laws.
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Nov 06, 2015
2 Resources
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Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 04, 2017
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Geomechanical Modeling for Thermal Spallation Drilling

Wells for Engineered Geothermal Systems (EGS) typically occur in conditions presenting significant challenges for conventional rotary and percussive drilling technologies: granitic rocks that reduce drilling speeds and cause substantial equipment wear. Thermal spallation drilling,...
Walsh, S. et al Lawrence Livermore National Laboratory
Aug 24, 2011
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Chlorite Dissolution Rates From 25 to 275 degrees and pH 3 to 10

We have calculated a chlorite dissolution rate equation at far from equilibrium conditions by combining new data (20 experiments at high temperature) with previously published data Smith et al. 2013 and Lowson et al. 2007. All rate data (from the 127 experiments) are tabulated in...
Lawrence Livermore National Laboratory
Sep 27, 2013
2 Resources
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Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: Data used in Geosphere Journal Article

This data submission is for Phase 2 of Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations, which focuses on multi-fluid (CO2 and brine) geothermal energy production and diurnal bulk energy storage in geologic settings that are suitable for ...
A., T. Lawrence Livermore National Laboratory
Jun 01, 2015
2 Resources
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Utah FORGE 2-2446: Report on Phase Field Modelling of Near-Wellbore Hydraulic Fracture Nucleation and Propagation

This is a report that describes the modelling of fracture nucleation and propagation in the near-wellbore region to understand the relationship between in situ stress and fracture patterns. A novel phase field formulation is described here, which represents fractures as a diffuse ...
Cusini, M. and Fei, F. Lawrence Livermore National Laboratory
Dec 31, 2023
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Surface Complexation Modeling of Terbium Biosorption onto E. Coli Bacterial Surfaces with Lanthanide Binding Tags

Lanthanide binding tags (LBTs) have been engineered onto native Escherichia coli (E. coli) bacterial surfaces to enhance extraction and recovery of rare earth elements (REEs). Three strains of E. coli were studied: (1) the native E. coli surface, (2) a mutant E. coli surface with ...
Jiao, Y. Lawrence Livermore National Laboratory
Apr 01, 2018
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Microearthquake Studies at the Salton Sea Geothermal Field

The objective of this project is to detect and locate microearthquakes to aid in the characterization of reservoir fracture networks. Accurate identification and mapping of the large numbers of microearthquakes induced in EGS is one technique that provides diagnostic information w...
Templeton, D. Lawrence Livermore National Laboratory
Oct 01, 2013
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Great Salt Lake Composition and Rare Earth Speciation Analysis

We have conducted aqueous speciation analyses of the Great Salt Lake (GSL) brine sample (Table 1) and a mock geo sample (Table 2) spiked with 1 ppb Tb and 100 ppb Tb. The GSL speciation (Figure 1) aligns with our basic speciation expectations that strong carbonate complexes would ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Apr 19, 2017
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Rare Earth Desorption Test with Citrate and Bicarbonate

LBT (lanthanide binding tag) cells were grown overnight in LB media with 0.05% Amp. 1:100 subculture taken from overnights, grown for 2 hours. LBT was induced with 0.002% arabinose added for 3 hours. REE adsorption was done by combining 350 ul (0.25% 1M MES, 12.5 uM Tb, and 12.5 u...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 01, 2017
1 Resources
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Fully Coupled Geomechanics and Discrete Flow Network Modeling of Hydraulic Fracturing for Geothermal Applications

The primary objective of our current research is to develop a computational test bed for evaluating borehole techniques to enhance fluid flow and heat transfer in enhanced geothermal systems (EGS). Simulating processes resulting in hydraulic fracturing and/or the remobilization of...
Fu, P. et al Lawrence Livermore National Laboratory
Jan 01, 2011
2 Resources
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Utah FORGE 2-2446: Closing the Loop Between In-situ Stress Complexity and EGS Fracture Complexity Workshop Presentation

This is a presentation on the Closing the Loop Between In-situ Stress Complexity and EGS Fracture Complexity project by Lawrence Livermore National Laboratory, presented by Dr. Matteo Cusini. The project's objective was to employ a combination of high-fidelity simulations and true...
Cusini, M. and Bunger, A. Lawrence Livermore National Laboratory
Sep 08, 2023
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Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: An Approach to Improve Energy Recovery and Mitigate Risk: FY1 Final Report The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal ...
A., T. Lawrence Livermore National Laboratory
Jan 01, 2012
8 Resources
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