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Recovery of Rare Earth Elements from Geothermal Fluids through Bacterial Cell Surface Adsorption

We summarized the FY17 and part of FY18 results of the analysis of the effect of several parameters (e.g., total dissolved solids, specific competing metals, pH, and temperature) on REE recovery from geothermal brine in a manuscript that was submitted to Environmental Science & Te...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jan 01, 2018
2 Resources
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Geomechanical Modeling for Thermal Spallation Drilling

Wells for Engineered Geothermal Systems (EGS) typically occur in conditions presenting significant challenges for conventional rotary and percussive drilling technologies: granitic rocks that reduce drilling speeds and cause substantial equipment wear. Thermal spallation drilling,...
Walsh, S. et al Lawrence Livermore National Laboratory
Aug 24, 2011
1 Resources
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Surface Complexation Modeling of Terbium Biosorption onto E. Coli Bacterial Surfaces with Lanthanide Binding Tags

Lanthanide binding tags (LBTs) have been engineered onto native Escherichia coli (E. coli) bacterial surfaces to enhance extraction and recovery of rare earth elements (REEs). Three strains of E. coli were studied: (1) the native E. coli surface, (2) a mutant E. coli surface with ...
Jiao, Y. Lawrence Livermore National Laboratory
Apr 01, 2018
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Design of an Airlift Bioreactor

An important consideration for the process design is cell immobilization-enabled flow-through operation. Large-scale biosorption relies on cells that are immobilized on a supporting substrate and used to 'attract' metal ions. Cell immobilization allows easy separation of the feed...
Jiao, Y. et al Lawrence Livermore National Laboratory
Mar 13, 2017
1 Resources
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Chlorite Dissolution Rates

Spreadsheets provides measured chlorite rate data from 100 to 300 degrees C at elevated CO2. Spreadsheet includes derived rate equation.
Carroll, S. Lawrence Livermore National Laboratory
Jul 01, 2013
1 Resources
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Applications of Geothermally-Produced Colloidal Silica in Reservoir Management Smart Gels

In enhanced geothermal systems (EGS) the reservoir permeability is often enhanced or created using hydraulic fracturing. In hydraulic fracturing, high fluid pressures are applied to confined zones in the subsurface usually using packers to fracture the host rock. This enhances r...
Hunt, J. et al Lawrence Livermore National Laboratory
Jan 31, 2013
2 Resources
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Illite Dissolution Rates and Equation (100 to 280 deg C)

The objective of this suite of experiments was to develop a useful kinetic dissolution expression for illite applicable over an expanded range of solution pH and temperature conditions representative of subsurface conditions in natural and/or engineered geothermal reservoirs. Usi...
Carroll, S. Lawrence Livermore National Laboratory
Oct 17, 2014
1 Resources
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Grain-Scale Failure in Thermal Spallation Drilling

Geothermal power promises clean, renewable, reliable and potentially widely-available energy, but is limited by high initial capital costs. New drilling technologies are required to make geothermal power financially competitive with other energy sources. One potential solution is ...
Walsh, S. et al Lawrence Livermore National Laboratory
Jan 01, 2012
1 Resources
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Rare Earth Desorption Test with Citrate and Bicarbonate

LBT (lanthanide binding tag) cells were grown overnight in LB media with 0.05% Amp. 1:100 subculture taken from overnights, grown for 2 hours. LBT was induced with 0.002% arabinose added for 3 hours. REE adsorption was done by combining 350 ul (0.25% 1M MES, 12.5 uM Tb, and 12.5 u...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 01, 2017
1 Resources
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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions

Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...
Carroll, S. et al Lawrence Livermore National Laboratory
Jul 01, 2013
1 Resources
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REE Adsorption Performance with Immobilized Caulobacter Biofilms

This submission includes data collected from experiments on the performance of rare earth adsorption by immobilized bacteria that accompany the FY18 Q2 and Q3 quarter reports. Relevant information from these reports is included in a resource below. The spreadsheet below includes d...
Jiao, Y. and Park, D. Lawrence Livermore National Laboratory
Apr 01, 2018
2 Resources
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Chlorite Dissolution Rates From 25 to 275 degrees and pH 3 to 10

We have calculated a chlorite dissolution rate equation at far from equilibrium conditions by combining new data (20 experiments at high temperature) with previously published data Smith et al. 2013 and Lowson et al. 2007. All rate data (from the 127 experiments) are tabulated in...
Lawrence Livermore National Laboratory
Sep 27, 2013
2 Resources
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Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C

FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Oct 01, 2013
2 Resources
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Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 04, 2017
1 Resources
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EGS Collab Experiment 1: Circulation Testing Processed data

This submission includes processed and reduced data for circulation testing that was conducted at the 164' fracture on the 4850 ft level of the Sanford Underground Research Facility. The circulation tests were done to test the flow through the 164' fracture in the EGS Collab Exper...
Fu, P. et al Lawrence Livermore National Laboratory
Apr 01, 2021
7 Resources
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Thermal Drawdown Induced Flow Channeling in Fractured Geothermal Reservoirs: Rock Mechanics and Rock Engineering

We investigate the flow-channeling phenomenon caused by thermal drawdown in fractured geothermal reservoirs. A discrete fracture network-based, fully coupled thermal "hydrological" mechanical simulator is used to study the interactions between fluid flow, temperature change, and t...
Fu, P. et al Lawrence Livermore National Laboratory
Nov 15, 2015
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Simulation Tools for Modeling Thermal Spallation Drilling on Multiple Scales

Widespread adoption of geothermal energy will require access to deeply buried resources in granitic basement rocks at high temperatures and pressures. Exploiting these resources necessitates novel methods for drilling, stimulation, and maintenance, under operating conditions that ...
Walsh, S. et al Lawrence Livermore National Laboratory
Jan 01, 2012
1 Resources
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Thermal Drawdown-Induced Flow Channeling in a Single Fracture in EGS

The evolution of flow pattern along a single fracture and its effects on heat production is a fundamental problem in the assessments of engineered geothermal systems (EGS). The channelized flow pattern associated with ubiquitous heterogeneity in fracture aperture distribution caus...
Guo, B. et al Lawrence Livermore National Laboratory
Nov 15, 2015
1 Resources
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