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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions
Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...
Carroll, S. et al Lawrence Livermore National Laboratory
Jul 01, 2013
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Silica Precipitation from Geothermal Brines: Effects of Iron Addition, Kinetics, Temperature, pH, and Brine Concentration
This document provides results of experiments aimed at removing silica from geothermal brines. All experiments were conducted with simulated brines. The data presented shows the effect of iron addition, kinetics, temperature, pH and brine concentration.
Renew, J. Southern Research Institute
Feb 06, 2016
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Chlorite, Biotite, Illite, Muscovite and Feldspar Dissolution Kinetics at Variable pH and Temperatures up to 280 deg C
Chemical reactions pose an important but poorly understood threat to EGS long-term success because of their impact on fracture permeability. This report summarizes the dissolution rate equations for layered silicates where data were lacking for geothermal systems. Here we report ...
Carroll, S. et al Lawrence Livermore National Laboratory
Feb 24, 2017
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Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C
FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Oct 01, 2013
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Chlorite Dissolution Rates
Spreadsheets provides measured chlorite rate data from 100 to 300 degrees C at elevated CO2. Spreadsheet includes derived rate equation.
Carroll, S. Lawrence Livermore National Laboratory
Jul 01, 2013
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Chemical Impact of Elevated CO2 on Geothermal Energy Production
Numerical simulations have shown that the use of supercritical CO2 instead of water as a heat transfer fluid yields significantly greater heat extraction rates for geothermal energy. If this technology is implemented successfully, it could increase geothermal energy production and...
Carroll, S. et al Lawrence Livermore National Laboratory
Jan 01, 2013
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Illite Dissolution Rates and Equation (100 to 280 deg C)
The objective of this suite of experiments was to develop a useful kinetic dissolution expression for illite applicable over an expanded range of solution pH and temperature conditions representative of subsurface conditions in natural and/or engineered geothermal reservoirs. Usi...
Carroll, S. Lawrence Livermore National Laboratory
Oct 17, 2014
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Chlorite Dissolution Rates From 25 to 275 degrees and pH 3 to 10
We have calculated a chlorite dissolution rate equation at far from equilibrium conditions by combining new data (20 experiments at high temperature) with previously published data Smith et al. 2013 and Lowson et al. 2007. All rate data (from the 127 experiments) are tabulated in...
Lawrence Livermore National Laboratory
Sep 27, 2013
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A Thermal-Hydrological-Chemical Model for the EGS Demonstration Project at Newberry Volcano, OR
Newberry Volcano in Central Oregon is the site of a Department of Energy funded Enhanced Geothermal System (EGS) Demonstration Project. Stimulation and production of an EGS is a strong perturbation to the physical and chemical environment, giving rise to coupled Thermal-Hydrologic...
Sonnenthal, E. et al National Energy Technology Laboratory
Jan 30, 2012
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