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Chlorite Dissolution Rates From 25 to 275 degrees and pH 3 to 10

We have calculated a chlorite dissolution rate equation at far from equilibrium conditions by combining new data (20 experiments at high temperature) with previously published data Smith et al. 2013 and Lowson et al. 2007. All rate data (from the 127 experiments) are tabulated in...

Lawrence Livermore National Laboratory

Sep 27, 2013
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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions

Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...

Carroll, S. et al Lawrence Livermore National Laboratory

Jul 01, 2013
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Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C

FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).

Carroll, S. and Smith, M. Lawrence Livermore National Laboratory

Oct 01, 2013
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Chemical Impact of Elevated CO2 on Geothermal Energy Production

Numerical simulations have shown that the use of supercritical CO2 instead of water as a heat transfer fluid yields significantly greater heat extraction rates for geothermal energy. If this technology is implemented successfully, it could increase geothermal energy production and...

Carroll, S. et al Lawrence Livermore National Laboratory

Jan 01, 2013
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Chlorite Dissolution Rates

Spreadsheets provides measured chlorite rate data from 100 to 300 degrees C at elevated CO2. Spreadsheet includes derived rate equation.

Carroll, S. Lawrence Livermore National Laboratory

Jul 01, 2013
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Illite Dissolution Rates and Equation (100 to 280 deg C)

The objective of this suite of experiments was to develop a useful kinetic dissolution expression for illite applicable over an expanded range of solution pH and temperature conditions representative of subsurface conditions in natural and/or engineered geothermal reservoirs. Usi...

Carroll, S. Lawrence Livermore National Laboratory

Oct 17, 2014
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REE Adsorption Performance with Immobilized Caulobacter Biofilms

This submission includes data collected from experiments on the performance of rare earth adsorption by immobilized bacteria that accompany the FY18 Q2 and Q3 quarter reports. Relevant information from these reports is included in a resource below. The spreadsheet below includes d...

Jiao, Y. and Park, D. Lawrence Livermore National Laboratory

Apr 01, 2018
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Recovery of Rare Earth Elements from Geothermal Fluids through Bacterial Cell Surface Adsorption

We summarized the FY17 and part of FY18 results of the analysis of the effect of several parameters (e.g., total dissolved solids, specific competing metals, pH, and temperature) on REE recovery from geothermal brine in a manuscript that was submitted to Environmental Science & Te...

Jiao, Y. et al Lawrence Livermore National Laboratory

Jan 01, 2018
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Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...

Jiao, Y. et al Lawrence Livermore National Laboratory

Jun 04, 2017
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Geomechanical Modeling for Thermal Spallation Drilling

Wells for Engineered Geothermal Systems (EGS) typically occur in conditions presenting significant challenges for conventional rotary and percussive drilling technologies: granitic rocks that reduce drilling speeds and cause substantial equipment wear. Thermal spallation drilling,...

Walsh, S. et al Lawrence Livermore National Laboratory

Aug 24, 2011
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EGS Collab Experiment 1: Circulation Testing Processed data

This submission includes processed and reduced data for circulation testing that was conducted at the 164' fracture on the 4850 ft level of the Sanford Underground Research Facility. The circulation tests were done to test the flow through the 164' fracture in the EGS Collab Exper...

Fu, P. et al Lawrence Livermore National Laboratory

Apr 01, 2021
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Thermal Drawdown Induced Flow Channeling in Fractured Geothermal Reservoirs: Rock Mechanics and Rock Engineering

We investigate the flow-channeling phenomenon caused by thermal drawdown in fractured geothermal reservoirs. A discrete fracture network-based, fully coupled thermal "hydrological" mechanical simulator is used to study the interactions between fluid flow, temperature change, and t...

Fu, P. et al Lawrence Livermore National Laboratory

Nov 15, 2015
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Simulation Tools for Modeling Thermal Spallation Drilling on Multiple Scales

Widespread adoption of geothermal energy will require access to deeply buried resources in granitic basement rocks at high temperatures and pressures. Exploiting these resources necessitates novel methods for drilling, stimulation, and maintenance, under operating conditions that ...