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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions
Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...
Carroll, S. et al Lawrence Livermore National Laboratory
Jul 01, 2013
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Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli
This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 04, 2017
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Chlorite Dissolution Rates
Spreadsheets provides measured chlorite rate data from 100 to 300 degrees C at elevated CO2. Spreadsheet includes derived rate equation.
Carroll, S. Lawrence Livermore National Laboratory
Jul 01, 2013
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Illite Dissolution Rates and Equation (100 to 280 deg C)
The objective of this suite of experiments was to develop a useful kinetic dissolution expression for illite applicable over an expanded range of solution pH and temperature conditions representative of subsurface conditions in natural and/or engineered geothermal reservoirs. Usi...
Carroll, S. Lawrence Livermore National Laboratory
Oct 17, 2014
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Great Salt Lake Composition and Rare Earth Speciation Analysis
We have conducted aqueous speciation analyses of the Great Salt Lake (GSL) brine sample (Table 1) and a mock geo sample (Table 2) spiked with 1 ppb Tb and 100 ppb Tb. The GSL speciation (Figure 1) aligns with our basic speciation expectations that strong carbonate complexes would ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Apr 19, 2017
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Rare Earth Desorption Test with Citrate and Bicarbonate
LBT (lanthanide binding tag) cells were grown overnight in LB media with 0.05% Amp. 1:100 subculture taken from overnights, grown for 2 hours. LBT was induced with 0.002% arabinose added for 3 hours. REE adsorption was done by combining 350 ul (0.25% 1M MES, 12.5 uM Tb, and 12.5 u...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 01, 2017
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Sustainable Self-Propping Shear Zones in EGS: Chlorite, Illite, and Biotite Rates and Report
Spreadsheet containing chlorite, illite, and biotite rate data and rate equations that can be used in reactive transport simulations. Submission includes a report on the development of the rate laws.
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Nov 06, 2015
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Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C
FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Oct 01, 2013
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Fully Coupled Geomechanics and Discrete Flow Network Modeling of Hydraulic Fracturing for Geothermal Applications
The primary objective of our current research is to develop a computational test bed for evaluating borehole techniques to enhance fluid flow and heat transfer in enhanced geothermal systems (EGS). Simulating processes resulting in hydraulic fracturing and/or the remobilization of...
Fu, P. et al Lawrence Livermore National Laboratory
Jan 01, 2011
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Using Fully Coupled Hydro-Geomechanical Numerical Test Bed to Study Reservoir Stimulation with Low Hydraulic Pressure
This paper documents our effort to use a fully coupled hydro-geomechanical numerical test bed to study using low hydraulic pressure to stimulate geothermal reservoirs with existing fracture network. In this low pressure stimulation strategy, fluid pressure is lower than the minimu...
Fu, P. et al Lawrence Livermore National Laboratory
Jan 31, 2012
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Chlorite, Biotite, Illite, Muscovite and Feldspar Dissolution Kinetics at Variable pH and Temperatures up to 280 deg C
Chemical reactions pose an important but poorly understood threat to EGS long-term success because of their impact on fracture permeability. This report summarizes the dissolution rate equations for layered silicates where data were lacking for geothermal systems. Here we report ...
Carroll, S. et al Lawrence Livermore National Laboratory
Feb 24, 2017
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The Value of Spatial Information for Determining Well Placement
The article and accompanying spreadsheet represent the information posteriors derived from synthetic data of magnetotellurics (MT). These were used to calculate value of information of MT for geothermal exploration. Information posteriors describe how well MT was able to locate t...
Trainor-Guitton, W. et al Lawrence Livermore National Laboratory
May 12, 2014
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Simulating Complex Fracture Systems in Geothermal Reservoirs Using an Explicitly Coupled Hydro-Geomechanical Model
Low permeability geothermal reservoirs can be stimulated by hydraulic fracturing to create Enhanced (or Engineered) Geothermal Systems (EGS) with higher permeability and improved heat transfer to increase heat production. In this paper, we document our effort to develop a numerica...
Carrigan, C. et al Lawrence Livermore National Laboratory
Jan 01, 2011
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Generalized Displacement Correlation Method for Estimating Stress Intensity Factors
This paper presents a generalized form of the displacement correlation method (the GDC method), which can use any linear or quadratic finite element type with homogeneous meshing without local refinement. These two features are critical for modeling dynamic fracture propagation pr...
Fu, P. et al Lawrence Livermore National Laboratory
Jan 01, 2012
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Investigation of Stimulation-Response Relationships for Complex Fracture Systems in Enhanced Geothermal Reservoirs
Hydraulic fracturing is currently the primary method for stimulating low-permeability geothermal reservoirs and creating Enhanced (or Engineered) Geothermal Systems (EGS) with improved permeability and heat production efficiency. Complex natural fracture systems usually exist in ...
Fu, P. et al Lawrence Livermore National Laboratory
Jan 01, 2011
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