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Lawrence Livermore National Laboratory×

Chlorite, Biotite, Illite, Muscovite and Feldspar Dissolution Kinetics at Variable pH and Temperatures up to 280 deg C

Chemical reactions pose an important but poorly understood threat to EGS long-term success because of their impact on fracture permeability. This report summarizes the dissolution rate equations for layered silicates where data were lacking for geothermal systems. Here we report ...
Carroll, S. et al Lawrence Livermore National Laboratory
Feb 24, 2017
2 Resources
0 Stars
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Applications of Geothermally-Produced Colloidal Silica in Reservoir Management Smart Gels

In enhanced geothermal systems (EGS) the reservoir permeability is often enhanced or created using hydraulic fracturing. In hydraulic fracturing, high fluid pressures are applied to confined zones in the subsurface usually using packers to fracture the host rock. This enhances r...
Hunt, J. et al Lawrence Livermore National Laboratory
Jan 31, 2013
2 Resources
0 Stars
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Sustainable Self-Propping Shear Zones in EGS: Chlorite, Illite, and Biotite Rates and Report

Spreadsheet containing chlorite, illite, and biotite rate data and rate equations that can be used in reactive transport simulations. Submission includes a report on the development of the rate laws.
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Nov 06, 2015
2 Resources
0 Stars
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Kinetics of Chlorite Dissolution at Elevated Temperatures and CO2 Conditions

Chlorite dissolution kinetics were measured under far from equilibrium conditions using a mixed-flow reactor over temperatures of 100-275 degrees C at pH values of 3.0-5.7 in a background solution matrix of 0.05 m NaCl. Over this temperature range, magnesium was released congruent...
Carroll, S. et al Lawrence Livermore National Laboratory
Jul 01, 2013
1 Resources
0 Stars
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Chlorite Dissolution Rates From 25 to 275 degrees and pH 3 to 10

We have calculated a chlorite dissolution rate equation at far from equilibrium conditions by combining new data (20 experiments at high temperature) with previously published data Smith et al. 2013 and Lowson et al. 2007. All rate data (from the 127 experiments) are tabulated in...
Lawrence Livermore National Laboratory
Sep 27, 2013
2 Resources
0 Stars
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REE Adsorption Performance with Immobilized Caulobacter Biofilms

This submission includes data collected from experiments on the performance of rare earth adsorption by immobilized bacteria that accompany the FY18 Q2 and Q3 quarter reports. Relevant information from these reports is included in a resource below. The spreadsheet below includes d...
Jiao, Y. and Park, D. Lawrence Livermore National Laboratory
Apr 01, 2018
2 Resources
0 Stars
Publicly accessible

Chlorite Dissolution Rates

Spreadsheets provides measured chlorite rate data from 100 to 300 degrees C at elevated CO2. Spreadsheet includes derived rate equation.
Carroll, S. Lawrence Livermore National Laboratory
Jul 01, 2013
1 Resources
0 Stars
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Improved Microseismicity Detection During Newberry EGS Stimulations

Effective enhanced geothermal systems (EGS) require optimal fracture networks for efficient heat transfer between hot rock and fluid. Microseismic mapping is a key tool used to infer the subsurface fracture geometry. Traditional earthquake detection and location techniques are oft...
Templeton, D. Lawrence Livermore National Laboratory
Oct 01, 2013
1 Resources
0 Stars
Publicly accessible

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: An Approach to Improve Energy Recovery and Mitigate Risk: FY1 Final Report The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal...
A., T. Lawrence Livermore National Laboratory
Jan 01, 2000
6 Resources
0 Stars
Publicly accessible

Improved Microseismicity Detection During Newberry EGS Stimulations

Effective enhanced geothermal systems (EGS) require optimal fracture networks for efficient heat transfer between hot rock and fluid. Microseismic mapping is a key tool used to infer the subsurface fracture geometry. Traditional earthquake detection and location techniques are oft...
Templeton, D. Lawrence Livermore National Laboratory
Nov 01, 2013
1 Resources
0 Stars
Publicly accessible

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: An Approach to Improve Energy Recovery and Mitigate Risk : FY1 Final Report The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal...
A., T. Lawrence Livermore National Laboratory
Jan 01, 2012
7 Resources
0 Stars
Publicly accessible

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: An Approach to Improve Energy Recovery and Mitigate Risk : FY1 Final Report The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal...
A., T. Lawrence Livermore National Laboratory
Jan 01, 2012
7 Resources
0 Stars
Publicly accessible

Illite Dissolution Rates and Equation (100 to 280 deg C)

The objective of this suite of experiments was to develop a useful kinetic dissolution expression for illite applicable over an expanded range of solution pH and temperature conditions representative of subsurface conditions in natural and/or engineered geothermal reservoirs. Usi...
Carroll, S. Lawrence Livermore National Laboratory
Oct 17, 2014
1 Resources
0 Stars
Publicly accessible

Mapping Fracture Network Creation with Microseismicity During EGS Demonstrations

This a report for the project "Mapping Fracture Network Creation with Microseismicity During EGS Demonstrations". Effective enhanced geothermal systems (EGS) require optimal fracture networks for efficient heat transfer between hot rock and fluid. Microseismic mapping is a key too...
Templeton, D. et al Lawrence Livermore National Laboratory
Apr 18, 2014
1 Resources
0 Stars
Publicly accessible

Techno-Economic Assessment for Integrating Biosorption into Rare Earth Recovery Process

The current uncertainty in the global supply of rare earth elements (REEs) necessitates the development of novel extraction technologies that utilize a variety of REE source materials. Herein, we examined the techno-economic performance of integrating a biosorption approach into ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jul 01, 2017
1 Resources
0 Stars
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Design of an Airlift Bioreactor

An important consideration for the process design is cell immobilization-enabled flow-through operation. Large-scale biosorption relies on cells that are immobilized on a supporting substrate and used to 'attract' metal ions. Cell immobilization allows easy separation of the feed...
Jiao, Y. et al Lawrence Livermore National Laboratory
Mar 13, 2017
1 Resources
0 Stars
Publicly accessible

Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 04, 2017
1 Resources
0 Stars
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Great Salt Lake Composition and Rare Earth Speciation Analysis

We have conducted aqueous speciation analyses of the Great Salt Lake (GSL) brine sample (Table 1) and a mock geo sample (Table 2) spiked with 1 ppb Tb and 100 ppb Tb. The GSL speciation (Figure 1) aligns with our basic speciation expectations that strong carbonate complexes would ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Apr 19, 2017
1 Resources
0 Stars
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Rare Earth Desorption Test with Citrate and Bicarbonate

LBT (lanthanide binding tag) cells were grown overnight in LB media with 0.05% Amp. 1:100 subculture taken from overnights, grown for 2 hours. LBT was induced with 0.002% arabinose added for 3 hours. REE adsorption was done by combining 350 ul (0.25% 1M MES, 12.5 uM Tb, and 12.5 u...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 01, 2017
1 Resources
0 Stars
Publicly accessible

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the ...
A., T. Lawrence Livermore National Laboratory
Jan 01, 2012
9 Resources
0 Stars
Publicly accessible

Rare Earth Adsorption and Desorption with PEGDA Beads

We synthesized PEGDA polymer hydrogel beads for cell embedding and compared REE biosorption with these beads via a gravity-driven flow through setup. One way to set up a flow through system is by cell encapsulation into polymer beads with a column setup similar to that used in th...
Jiao, Y. et al Lawrence Livermore National Laboratory
Mar 01, 2017
1 Resources
0 Stars
Publicly accessible

Utah FORGE: Powder X-ray Diffraction Data from Well 16A(78)-32 Core

This dataset from Lawrence Livermore National Laboratory (LLNL) consists of four raw X-ray diffraction (XRD) scans and preliminary results of quantitative XRD analysis. The scanned samples were prepared from four subcores, which came from various depths of the FORGE well 16A(78)-3...
Kroll, K. et al Lawrence Livermore National Laboratory
Jul 27, 2023
1 Resources
0 Stars
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Surface Complexation Modeling of Terbium Biosorption onto E. Coli Bacterial Surfaces with Lanthanide Binding Tags

Lanthanide binding tags (LBTs) have been engineered onto native Escherichia coli (E. coli) bacterial surfaces to enhance extraction and recovery of rare earth elements (REEs). Three strains of E. coli were studied: (1) the native E. coli surface, (2) a mutant E. coli surface with ...
Jiao, Y. Lawrence Livermore National Laboratory
Apr 01, 2018
1 Resources
0 Stars
Publicly accessible

Techno-Economic Assessment for Integrating Biosorption into Rare Earth Recovery Process

The current uncertainty in the global supply of rare earth elements (REEs) necessitates the development of novel extraction technologies that utilize a variety of REE source materials. Herein, we examined the techno-economic performance of integrating a biosorption approach into a...
Jiao, Y. et al Lawrence Livermore National Laboratory
Oct 09, 2017
1 Resources
0 Stars
Publicly accessible

Chlorite Dissolution Kinetics at Variable pH and Temperatures up to 275C

FY13 annual report describing the calculations and results associated with the data and dissolution rate contained in "Chlorite Kinetic Dissolution Data and Rate" (linked below).
Carroll, S. and Smith, M. Lawrence Livermore National Laboratory
Oct 01, 2013
2 Resources
0 Stars
Publicly accessible
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