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R245fa Adsorption on MIL-101

Adsorption isotherms for R245fa on metal organic heat carrier candidate MIL-101
McGrail, P. Pacific Northwest National Laboratory
Oct 22, 2013
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Rare Earth Element Biomining from the Great Salt Lake Brine Using Engineered E. Coli

This data describes rare earth element adsorption onto E. coli cells engineered to express a lanthanide binding tag (LBT). We used a Great Salt Lake synthetic solution as the background matrix with Tb added to 1-10,000 ppb, concentrations much lower than the competing ions presen...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 04, 2017
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EGS Collab Experiment 1: DNA tracer data on transport through porous media

This submission contains DNA tracer data that supports the analysis and conclusions of the publication, "DNA tracer transport through porous media The effect of DNA length and adsorption." https://doi.org/10.1029/2020WR028382. This experiment used DNA as an artificial reservoir t...
Zhang, Y. et al Stanford University
Nov 21, 2020
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Protocol for Regeneration of Ligand-Depleted Adsorption Media for Rare Earth Element Recovery from Geothermal Brine

Description of experimental protocol used to characterize the effectiveness of regenerating ligand-based adsorption media through the addition of ligands when media were previously depleted of ligands during use. Results of the effectiveness of this regeneration are also described.
Stull, D. Tusaar Corp.
May 24, 2016
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Rare Earth Adsorption and Desorption with PEGDA Beads

We synthesized PEGDA polymer hydrogel beads for cell embedding and compared REE biosorption with these beads via a gravity-driven flow through setup. One way to set up a flow through system is by cell encapsulation into polymer beads with a column setup similar to that used in th...
Jiao, Y. et al Lawrence Livermore National Laboratory
Mar 01, 2017
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REE Adsorption Performance with Immobilized Caulobacter Biofilms

This submission includes data collected from experiments on the performance of rare earth adsorption by immobilized bacteria that accompany the FY18 Q2 and Q3 quarter reports. Relevant information from these reports is included in a resource below. The spreadsheet below includes d...
Jiao, Y. and Park, D. Lawrence Livermore National Laboratory
Apr 01, 2018
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Recovery of Rare Earth Elements from Geothermal Fluids through Bacterial Cell Surface Adsorption

We summarized the FY17 and part of FY18 results of the analysis of the effect of several parameters (e.g., total dissolved solids, specific competing metals, pH, and temperature) on REE recovery from geothermal brine in a manuscript that was submitted to Environmental Science & Te...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jan 01, 2018
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Rare Earth Desorption Test with Citrate and Bicarbonate

LBT (lanthanide binding tag) cells were grown overnight in LB media with 0.05% Amp. 1:100 subculture taken from overnights, grown for 2 hours. LBT was induced with 0.002% arabinose added for 3 hours. REE adsorption was done by combining 350 ul (0.25% 1M MES, 12.5 uM Tb, and 12.5 u...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jun 01, 2017
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Gd Uptake Experiments for Preliminary Set of Functionalized Adsorbents (With Content Model)

These data summarize adsorption experiments conducted with Gd in 0.5 M NaCl. Results represent preliminary, proof-of-concept data utilizing fine-powder silica gel as the adsorbent support. Future testing will focus on larger, application-appropriate beads.
Noack, C. Carnegie Mellon University
Jul 01, 2015
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Chelating Resins for Selective Separation and Recovery of Rare Earth Elements from Low Temperature Geothermal Water

Study on the use of organic ligands to extract lanthanides from low temperature geothermal water.
Callura, J. Carnegie Mellon University
Dec 31, 2016
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Comparison of Rare Earth Element Sorption Between Fresh and Partially Loaded Media Using Simulated Geothermal Brine

A study comparing the REE sorption characteristics of fresh ligand-based sorption media and media partially loaded with REEs when exposed to a simulated geothermal brine with known mineral concentrations, REE7. Sorption rates were tested using microcosm shaker tests. Results sugg...
Stull, D. Tusaar Corp.
May 24, 2016
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Lithium and Manganese Uptake Data from Initial Set of Imprinted Polymers

Batch tests of cross-linked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45 deg C .
Ventura, S. SRI International
Mar 27, 2015
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In-Situ Process for Sorption and Stripping of Rare Earth Elements from Simulated Geothermal Brine

Description of a conceptual commercial process to remove rare earth elements (REEs) from geothermal brine, based on a small-scale laboratory experiment to load, strip, and regenerate a ligand-based media used to adsorb REEs from a simulated brine doped with known mineral concentra...
Stull, D. Tusaar Corp.
May 24, 2016
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Design of an Airlift Bioreactor

An important consideration for the process design is cell immobilization-enabled flow-through operation. Large-scale biosorption relies on cells that are immobilized on a supporting substrate and used to 'attract' metal ions. Cell immobilization allows easy separation of the feed...
Jiao, Y. et al Lawrence Livermore National Laboratory
Mar 13, 2017
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Method to Recover Media Ligand Losses During Sorption of Rare Earth Elements from Simulated Geothermal Brines

This document describes the method and results of an in-situ experiment used to confirm that ligand bleed from a sorptive media can be contained. The experiment focused on maintaining the media's sorption of rare earth elements (REE) obtained from a simulated geothermal brine dop...
Stull, D. Tusaar Corp.
May 24, 2016
2 Resources
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Great Salt Lake Composition and Rare Earth Speciation Analysis

We have conducted aqueous speciation analyses of the Great Salt Lake (GSL) brine sample (Table 1) and a mock geo sample (Table 2) spiked with 1 ppb Tb and 100 ppb Tb. The GSL speciation (Figure 1) aligns with our basic speciation expectations that strong carbonate complexes would ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Apr 19, 2017
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Experimental Parameters Affecting Stripping of Rare Earth Elements from Loaded Sorptive Media in Simulated Geothermal Brines

Experimental results from several studies exploring the impact of pH and acid volume on the stripping of rare earth elements (REEs) loaded onto ligand-based media via an active column. The REEs in this experiment were loaded onto the media through exposure to a simulated geother...
Stull, D. Tusaar Corp.
May 24, 2016
2 Resources
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Surface Complexation Modeling of Terbium Biosorption onto E. Coli Bacterial Surfaces with Lanthanide Binding Tags

Lanthanide binding tags (LBTs) have been engineered onto native Escherichia coli (E. coli) bacterial surfaces to enhance extraction and recovery of rare earth elements (REEs). Three strains of E. coli were studied: (1) the native E. coli surface, (2) a mutant E. coli surface with ...
Jiao, Y. Lawrence Livermore National Laboratory
Apr 01, 2018
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Techno-Economic Assessment for Integrating Biosorption into Rare Earth Recovery Process

The current uncertainty in the global supply of rare earth elements (REEs) necessitates the development of novel extraction technologies that utilize a variety of REE source materials. Herein, we examined the techno-economic performance of integrating a biosorption approach into ...
Jiao, Y. et al Lawrence Livermore National Laboratory
Jul 01, 2017
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EGS Collab Experiment 1: TOUGH2-CSM Simulation of Embedded Natural Fractures and Chemical Tracer Transport and Sorption

The EGS Collab SIGMA-V project is a multi-lab and university collaborative research project that is being undertaken at the Sanford Underground Research Facility (SURF) in South Dakota. The project consists of studying stimulation, fluid-flow, and heat transfer processes at a scal...
Johnston, B. et al National Renewable Energy Laboratory
Jun 07, 2019
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